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For a gas obeying Charles's Law, a plot of V versus 1/T will give a straight line passing through the origin.

A) True
B) False

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The rate of diffusion of a gas is inversely proportional to its molar mass.

A) True
B) False

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According to the postulates of kinetic-molecular theory, the molecules of all gases at a given temperature have the same average kinetic energy.

A) True
B) False

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Use the van der Waals equation for real gases to calculate the pressure exerted by 1.00 mole of ammonia at 27 °\degree C in a 750-mL container. (a = 4.17 L2*atm/mol2, b = 0.0371 L/mol)


A) 23.2 atm
B) 27.1 atm
C) 32.8 atm
D) 42.0 atm
E) 32.8 torr

F) C) and D)
G) B) and E)

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The ozone layer is important because


A) ozone absorbs low energy radiation which warms the troposphere.
B) ozone purifies the atmosphere by reacting with excess fluorocarbons.
C) ozone absorbs ultraviolet radiation.
D) ozone reflects high energy radiation such as X-rays and gamma rays.
E) humans need to breathe air containing some ozone.

F) C) and D)
G) A) and B)

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A compound composed of carbon, hydrogen, and chlorine effuses through a pinhole 0.411 times as fast as neon. Select the correct molecular formula for the compound.


A) CHCl3
B) CH2Cl2
C) C2H2Cl2
D) C2H3Cl
E) CCl4

F) B) and C)
G) B) and E)

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"The rate of effusion of a gas is inversely proportional to the square root of its molar mass" is a statement of ______________________ Law.


A) Charles's
B) Graham's
C) Dalton's
D) Avogadro's
E) Boyle's

F) C) and D)
G) B) and D)

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Which of the lines on the figure below is the best representation of the relationship between the volume of a gas and its pressure, other factors remaining constant? Which of the lines on the figure below is the best representation of the relationship between the volume of a gas and its pressure, other factors remaining constant?   A)  a B)  b C)  c D)  d E)  e


A) a
B) b
C) c
D) d
E) e

F) All of the above
G) A) and B)

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State Avogadro's Law.

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Equal volumes of gas...

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State Amontons's Law and illustrate it with a graph, using standard x-y coordinate axes. Be sure to label the axes unambiguously with the correct gas variables.

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At constant volume, the pressure of a fi...

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A flask containing argon gas is connected to an closed-ended mercury manometer. The closed end is under vacuum. If the mercury level in the closed arm is 230. mm above that in the arm connected to the flask, what is the argon pressure, in torr?


A) -230.
B) 230.
C) 530.
D) 790.
E) None of these choices is correct.

F) None of the above
G) B) and E)

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A sample of oxygen gas has its absolute temperature halved while the pressure of the gas remained constant. If the initial volume is 400 mL, what is the final volume?


A) 20 mL
B) 133 mL
C) 200 mL
D) 400 mL
E) 800 mL

F) A) and B)
G) A) and C)

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The ideal gas law tends to become inaccurate when


A) the pressure is lowered and molecular interactions become significant.
B) the pressure is raised and the temperature is lowered.
C) the temperature is raised above the temperature of STP.
D) large gas samples are involved.
E) the volume expands beyond the standard molar volume.

F) A) and B)
G) A) and C)

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Select the gas with the highest average kinetic energy per mole at 298 K.


A) O2
B) CO2
C) H2O
D) H2
E) All have the same average kinetic energy.

F) D) and E)
G) A) and B)

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"The total pressure in a mixture of unreacting gases is equal to the sum of the partial pressures of the individual gases" is a statement of __________________ Law.


A) Charles's
B) Graham's
C) Boyle's
D) Avogadro's
E) Dalton's

F) All of the above
G) C) and D)

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A gas consists of 85.7 % carbon and 14.3% hydrogen, by weight. A sample of this gas weighing 0.673 g occupies 729 mL at a pressure of 720.0 mmHg and a temperature of 77 °\degree C. Calculate its empirical and molecular formulas.


A) CH, C2H2
B) CH2, C2H4
C) CH2, C3H6
D) CH3, C2H6
E) CH4, CH4

F) All of the above
G) C) and D)

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. If the partial pressure of argon is 200. torr, what is the pressure of methane, in torr?


A) 80.0 torr
B) 200. torr
C) 256 torr
D) 500. torr
E) 556 torr

F) D) and E)
G) C) and E)

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Small quantities of hydrogen can be prepared by the addition of hydrochloric acid to zinc. A sample of 195 mL of hydrogen was collected over water at 25 °\degree C and 753 torr. What mass of hydrogen was collected? (Pwater = 24 torr at 25 °\degree C)


A) 0.00765 g
B) 0.0154 g
C) 0.0159 g
D) 0.0164 g
E) 0.159 g

F) A) and E)
G) A) and D)

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A flask with a volume of 3.16 L contains 9.33 grams of an unknown gas at 32.0 °\degree C and 1.00 atm. What is the molar mass of the gas?


A) 7.76 g/mol
B) 66.1 g/mol
C) 74.0 g/mol
D) 81.4 g/mol
E) 144 g/mol

F) C) and D)
G) B) and D)

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A carbon dioxide sample weighing 44.0 g occupies 32.68 L at 65 °\degree C and 645 torr. What is its volume at STP?


A) 22.4 L
B) 31.1 L
C) 34.3 L
D) 35.2 L
E) 47.7 L

F) A) and B)
G) B) and E)

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