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How many moles of bromide ions are present in 750.0 mL of 1.35 M MgBr2?


A) 0.506 mol
B) 1.01 mol
C) 2.03 mol
D) 3.04 mol
E) None of these choices is correct.

F) A) and E)
G) A) and B)

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Isoamyl salicylate (м = 208.25 g/mol) has a pleasant aroma and is used in perfumes and soaps. Which of the following combinations gives a 0.75 m solution of isoamyl salicylate in ethyl alcohol (d = 0.7893 g/mL) ?


A) 117.2 g isoamyl salicylate in 950.0 mL of ethyl alcohol
B) 117.2 g isoamyl salicylate in 750.0 mL of ethyl alcohol
C) 117.2 g isoamyl salicylate in 750.0 mL of solution
D) 117.2 g isoamyl salicylate in 592.0 g of ethyl alcohol
E) None of these choices is correct.

F) A) and E)
G) C) and D)

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A saturated solution of carbon dioxide in water contains 3.00 g of CO2 when the CO2 partial pressure is 8.0 atm. What mass of CO2 will escape if the partial pressure is lowered to 3.2 atm?


A) 0.90 g
B) 1.20 g
C) 1.40 g
D) 1.80 g
E) 2.20 g

F) A) and D)
G) A) and B)

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A solution of ethanol (C2H6O) in water is sometimes used as a disinfectant. 1.00 L of this solution contains 553 g of ethanol and 335 g of water. What is the molality of the ethanol in this solution?


A) 0.392 m
B) 0.608 m
C) 13.5 m
D) 33.6 m
E) 35.8 m

F) D) and E)
G) C) and D)

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The concentration of iodine in sea water is 60. parts per billion by mass. If one assumes that the iodine exists in the form of iodide anions, what is the molarity of iodide in sea water? (The density of sea water is 1.025 g/mL.)


A) 4.8 *10¯13 M
B) 4.8 *10¯10 M
C) 4.8*10¯7 M
D) 4.7 * 10¯4 M
E) 4.7 *10¯1 M

F) A) and E)
G) C) and D)

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All solutions are mixtures.

A) True
B) False

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A 2.0% (w/v) solution of sodium hydrogen citrate, Na2C6H6O7, which also contains 2.5% (w/v) of dextrose, C6H12O6, is used as an anticoagulant for blood which is to be used for transfusions. What is the molarity of the sodium hydrogen citrate in the solution?


A) 0.085 M
B) 0.19 M
C) 0.53 M
D) 1.2 M
E) 1.3 M

F) None of the above
G) C) and D)

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The solubility of gases in water increases with increase in the pressure of the gas.

A) True
B) False

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Calculate the molarity of a solution prepared by diluting 1.85 L of 6.5 M KOH to 11.0 L.


A) 0.28 M
B) 0.91 M
C) 1.1 M
D) 3.1 M
E) 3.9 M

F) A) and B)
G) C) and D)

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Consider the expression below, showing the terms which contribute to the heat of solution, ∆Hsoln: ∆Hsoln = ∆Hsolute + ∆Hsolvent + ∆Hmix Which of the following sets correctly shows the signs (positive or negative) of the three terms on the right hand side of the equation?


A) ∆Hsolute > 0; ∆Hsolvent > 0; ∆Hmix > 0
B) ∆Hsolute <0; ∆Hsolvent < 0; ∆Hmix < 0
C) ∆Hsolute > 0; ∆Hsolvent > 0; ∆Hmix < 0
D) ∆Hsolute < 0; ∆Hsolvent < 0; ∆Hmix > 0
E) ∆Hsolute < 0; ∆Hsolvent > 0; ∆Hmix < 0

F) B) and E)
G) B) and D)

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A solution of ethanol (C2H6O) in water is sometimes used as a disinfectant. 1.00 L of this solution contains 553 g of ethanol and 335 g of water. What is the mole fraction of ethanol in this solution?


A) 0.377
B) 0.392
C) 0.553
D) 0.608
E) 0.623

F) A) and B)
G) C) and D)

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Select the type of interaction which best describes the attraction between Mg2+ ions and water molecules.


A) dipole-dipole
B) dipole-induced dipole
C) ion-dipole
D) ion-induced dipole
E) ion-hydrogen bond

F) C) and D)
G) A) and B)

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Gases with high boiling points tend to be more soluble in water than ones with low boiling points.

A) True
B) False

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List five important intermolecular forces that operate in globular proteins, and explain what parts of the molecule are involved in these forces.

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1. Ion-dipole forces. These exist betwee...

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Children under the age of six with more than 0.10 ppm of lead in their blood can suffer a reduction in I.Q. or have behavior problems. What is the molality of a solution which contains 0.10 ppm of lead?


A) 4.8 *10¯10 m
B) 4.8*10¯7 m
C) 4.8 *10¯4 m
D) 4.8 *10¯1 m
E) None of these choices is correct.

F) B) and D)
G) None of the above

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Barbiturates are synthetic drugs used as sedatives and hypnotics. Barbital (? = 184.2 g/mol) is one of the simplest of these drugs. What is the boiling point of a solution prepared by dissolving 42.5 g of barbital in 825 g of acetic acid? Kb = 3.07 °\degree C/m; boiling point of pure acetic acid = 117.9 °\degree C


A) 117.0 °\degree C
B) 117.7 °\degree C
C) 118.1 °\degree C
D) 118.8 °\degree C
E) >120 °\degree C

F) C) and E)
G) None of the above

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If the density of a solution is less than 1.0 g/mL, its molarity will be greater than its molality.

A) True
B) False

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A 0.100 m MgSO4 solution has a freezing point of -0.23 °\degree C. What is the van't Hoff factor for this solution? Kf = 1.86 °\degree C/m


A) 0.62
B) 1.0
C) 1.2
D) 2.0
E) 4.0

F) D) and E)
G) B) and D)

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How many moles of sulfate ions are present in 1.0 L of 0.5 M Li2SO4?


A) 0.5 mol
B) 1.0 mol
C) 1.5 mol
D) 2.0 mol
E) 3.0 mol

F) C) and E)
G) B) and E)

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What volume of concentrated (14.7 M) phosphoric acid is needed to prepare 25.0 L of 3.0 M H3PO4?


A) 0.20 L
B) 0.57 L
C) 1.8 L
D) 3.6 L
E) 5.1 L

F) C) and D)
G) A) and D)

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