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What is the molecular shape of SiF6 as predicted by the VSEPR theory? What is the molecular shape of SiF<sub>6</sub><sup>2¯</sup> as predicted by the VSEPR theory?   A)  trigonal bipyramidal B)  hexagonal C)  tetrahedral D)  see-saw E)  octahedral


A) trigonal bipyramidal
B) hexagonal
C) tetrahedral
D) see-saw
E) octahedral

F) A) and C)
G) B) and E)

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Boron never achieves an octet in any of its compounds.

A) True
B) False

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List all possible molecular geometries (shapes) for a nonpolar molecule with the formula AX4.


A) tetrahedral
B) seesaw
C) square planar
D) either tetrahedral or square planar
E) All of these choices are possible.

F) A) and E)
G) C) and D)

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According to VSEPR theory, a molecule with the general formula AX4 will have a ______ molecular shape.


A) bent
B) trigonal planar
C) trigonal pyramidal
D) square planar
E) tetrahedral

F) B) and D)
G) C) and D)

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In the following Lewis structure for phosphate, phosphorus has a formal charge of ____ and an oxidation number of ____. In the following Lewis structure for phosphate, phosphorus has a formal charge of ____ and an oxidation number of ____.   A)  0, -3 B)  0, 5 C)  5, -3 D)  5, 5 E)  3, 5


A) 0, -3
B) 0, 5
C) 5, -3
D) 5, 5
E) 3, 5

F) B) and E)
G) B) and C)

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Draw Lewis structures, showing all valence electrons, for: A) N B) Br¯ c. O2 d. SO4

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Draw Lewis structures, showing all valence electrons, for the following species: A) S b. CO C) SO2 d. CH3OH

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Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI3 which minimizes formal charges.


A) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> which minimizes formal charges. A)    B)    C)    D)    E)
B) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> which minimizes formal charges. A)    B)    C)    D)    E)
C) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> which minimizes formal charges. A)    B)    C)    D)    E)
D) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> which minimizes formal charges. A)    B)    C)    D)    E)
E) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> which minimizes formal charges. A)    B)    C)    D)    E)

F) A) and E)
G) A) and B)

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Hydrazine, N2H4, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure.


A) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices is correct.
B) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices is correct.
C) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices is correct.
D) Hydrazine, N<sub>2</sub>H<sub>4</sub>, is a good reducing agent that has been used as a component in rocket fuels. Select its Lewis structure. A)    B)    C)    D)    E)  None of these choices is correct.
E) None of these choices is correct.

F) None of the above
G) A) and E)

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Explain what is meant by "dipole moment", and give an example of a molecule which has polar bonds but which does not itself have a dipole moment.

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A dipole moment arises in a molecule whe...

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In order for a non-cyclic triatomic molecule to be bent, VSEPR theory requires that there must be two lone pairs on the central atom.

A) True
B) False

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According to VSEPR theory, a molecule with the general formula AX3 will have a ______ molecular shape.


A) linear
B) bent
C) trigonal planar
D) tetrahedral
E) trigonal pyramidal

F) B) and D)
G) B) and E)

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What is the molecular shape of ClCN as predicted by the VSEPR theory? (Carbon is the central atom.)


A) linear
B) bent
C) angular
D) trigonal
E) None of these choices is correct.

F) A) and E)
G) C) and D)

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In a Lewis structure for a molecule or ion, the sum of the formal charges on the atoms is equal to the charge on the molecule or ion.

A) True
B) False

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The best Lewis structure for sulfuric acid has zero formal charges, sulfur as the central atom, and no bonds between S and H. How many single and double bonds, respectively, are there in this Lewis structure?


A) 2 single, 4 double
B) 4 single, 2 double
C) 4 single, no double
D) 6 single, no double
E) 5 single, 1 double

F) A) and D)
G) B) and D)

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How many faces and how many vertexes (corners) , respectively, are there in a trigonal bipyramid?


A) 4 and 4
B) 5 and 5
C) 5 and 6
D) 6 and 5
E) 6 and 8

F) A) and B)
G) C) and D)

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Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl2.


A) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these structures is suitable for SOCl<sub>2</sub>.
B) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these structures is suitable for SOCl<sub>2</sub>.
C) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these structures is suitable for SOCl<sub>2</sub>.
D) Thionyl chloride is used as an oxidizing and chlorinating agent in organic chemistry. Select the best Lewis structure for SOCl<sub>2</sub>. A)    B)    C)    D)    E)  None of these structures is suitable for SOCl<sub>2</sub>.
E) None of these structures is suitable for SOCl2.

F) A) and D)
G) C) and D)

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Which one of the following molecules does not have a dipole moment?


A) CS2
B) H2S
C) CH2Cl2
D) PH3
E) CH2O

F) A) and B)
G) C) and D)

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Considering all the bonds in a molecule with trigonal bipyramidal geometry, what are the bond angles present?


A) 120 °\degree only
B) 90 °\degree only
C) 180 °\degree only
D) 60 °\degree and 90 °\degree only
E) 90 °\degree , 120 °\degree and 180 °\degree

F) C) and D)
G) A) and D)

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What is the molecular shape of ClF4¯ as predicted by the VSEPR theory?


A) square pyramidal
B) square planar
C) see-saw
D) octahedral
E) tetrahedral

F) B) and E)
G) A) and B)

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