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Ammonium chloride is used as an electrolyte in dry cells. Which statement about a 0.10 M solution of NH4Cl is correct?


A) The solution is weakly basic.
B) The solution is strongly basic.
C) The solution is neutral.
D) The solution is acidic.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) All of the above
G) B) and E)

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Calculate the concentration of malonate ion (C3H2O42-) in a 0.200 M solution of malonic acid (C3H4O4) . (For malonic acid, Ka1 = 1.4 × 10-3, Ka2 = 2.0 × 10-6.)


A) 2.8 × 10-4 M
B) 0.016 M
C) 1.8 × 10-4 M
D) 1.4 × 10-3 M
E) 2.0 × 10-6 M

F) A) and B)
G) A) and C)

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Hard water deposits (calcium carbonate) have built up around your bathroom sink. Which of these substances would be most effective in dissolving the deposits?


A) ammonia
B) bleach (sodium hypochlorite)
C) lye (sodium hydroxide)
D) vinegar (acetic acid)

E) A) and B)
F) A) and C)

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Which is the strongest base?


A) CH3NH2, Kb = 4.4 × 10-4
B) C5H5N, Kb = 1.7 × 10-9
C) H2NCONH2, Kb = 1.5 × 10-14
D) NH3, Kb = 1.8 × 10-5
E) C2H5NH2, Kb = 5.6 × 10-4

F) A) and D)
G) A) and B)

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Find the pH of a 0.183 M aqueous solution of hypobromous acid (HOBr) , for which Ka = 2.06 × 10-9.


A) 4.712
B) 8.686
C) 0.738
D) 4.576
E) 9.288

F) C) and D)
G) B) and E)

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What is the conjugate acid of the hydroxide ion?


A) H3O+
B) OH-
C) H3O
D) OH
E) H2O

F) B) and D)
G) All of the above

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Iodine trichloride, ICl3, will react with a chloride ion to form ICl4-. Which acts as a Lewis acid this reaction?


A) ICl4-
B) ICl3
C) Cl-
D) I3+
E) The solvent

F) A) and E)
G) A) and B)

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What is the value of the equilibrium constant for the autoionization of water at 25°C?


A) 1.0 × 10-7
B) 1.0 × 10-14
C) 1.0 × 1014
D) 1.0 × 107
E) 14

F) B) and E)
G) B) and D)

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What is the pOH of a 0.025 M HI solution?


A) 0.025
B) 0.94
C) 1.60
D) 12.40
E) 10.31

F) C) and D)
G) None of the above

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Since zirconium is a metal, ZrO2 is expected to be a/an ________ oxide.


A) acidic
B) ionic
C) amphoteric
D) neutral
E) basic

F) B) and E)
G) A) and E)

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Which is a basic oxide?


A) NO2
B) H2O
C) Na2O
D) SnO
E) SO2

F) None of the above
G) B) and C)

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Which is the strongest acid?


A) HBrO4
B) HBr
C) HBrO2
D) HBrO
E) HBrO3

F) B) and C)
G) A) and E)

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Which is the strongest acid?


A) HBrO3
B) HClO
C) HBrO2
D) HBrO
E) HClO3

F) B) and D)
G) A) and B)

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The first ionization constant Ka1 is always smaller than the second ionization constant Ka2 for the ionization of a diprotic acid.

A) True
B) False

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What is the concentration of H+ in a 0.025 M HCl solution?


A) 0
B) 0.013 M
C) 0.025 M
D) 0.050 M
E) 0.010 M

F) D) and E)
G) B) and D)

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The ammonium ion, NH4+, is a weak acid.

A) True
B) False

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What is the name of a proton donor in an acid-base reaction?


A) Arrhenius acid
B) Arrhenius base
C) Brønsted acid
D) Brønsted base
E) Lewis base

F) A) and E)
G) A) and B)

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What is the pH of a 0.050 M triethylamine, (C2H5) 3N, solution? Kb for triethylamine is 5.3 × 10-4.


A) 11.69
B) 8.68
C) 5.32
D) 2.31
E) 1.30

F) A) and E)
G) C) and D)

Correct Answer

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Calcium oxide, CaO, also known as quick lime, may react with carbon dioxide to form calcium carbonate, CaCO3. Which acts as a Lewis acid in the reaction?


A) Ca2+
B) O2-
C) CO2
D) CaCO3
E) CO32-

F) A) and D)
G) B) and C)

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Formic acid, which is a component of some insect venoms, has a Ka = 1.8 × 10-4. What is the [H3O+] in a solution that is initially 0.10 M formic acid, HCOOH?


A) 4.2 × 10-3 M
B) 8.4 × 10-3 M
C) 1.8 × 10-4 M
D) 1.8 × 10-5 M
E) 1.8 × 10-6 M

F) A) and C)
G) D) and E)

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