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The density of water is 1.00 g/mL at 4°C. How many water molecules are present in 6.25 mL of water at this temperature? (NA = 6.022 × 1023 mol-1)


A) 6.27 × 1023 molecules
B) 3.76 × 1024 molecules
C) 2.09 × 1023 molecules
D) 6.02 × 1023 molecules
E) 0.347 molecules

F) B) and E)
G) C) and D)

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If 119.3 g of PCl5 are formed from the reaction of 61.3 g Cl2 with excess PCl3, what is the percent yield? PCl3(g) + Cl2(g) → PCl5(g)


A) 94.6%
B) 66.3%
C) 57.3%
D) 51.3%
E) 48.6%

F) A) and E)
G) B) and E)

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Aluminum reacts with bromine to form aluminum bromide (used as an acid catalyst in organic synthesis) . Al(s) + Br2(l) → Al2Br6(s) [unbalanced] How many moles of Al are needed to form 2.43 mol of Al2Br6?


A) 7.29 mol
B) 4.86 mol
C) 2.43 mol
D) 1.62 mol
E) 1.22 mol

F) C) and D)
G) C) and E)

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The first step in the Ostwald process for producing nitric acid is as follows: 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g) . If the reaction of 15.0 g of ammonia with 15.0 g of oxygen gas yields 8.70 g of nitric oxide, what is the percent yield of this reaction?


A) 29.0%
B) 32.9%
C) 49.5%
D) 61.8%
E) 77.3%

F) None of the above
G) C) and E)

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Many compounds can be represented with the same empirical formula.

A) True
B) False

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Calculate the formula mass of ammonium arsenate, (NH4) 3AsO4.


A) 417.80 amu
B) 193.05 amu
C) 165.02 amu
D) 156.96 amu
E) 108.96 amu

F) A) and B)
G) B) and D)

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Hydrochloric acid can be prepared by the following reaction: 2NaCl(s) + H2SO4(aq) → 2HCl(g) + Na2SO4(s) What mass of HCl can be prepared from 2.00 mol H2SO4 and 150. g NaCl?


A) 2.57 g
B) 46.8 g
C) 93.6g
D) 146 g
E) 167g

F) C) and D)
G) A) and D)

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What is the average mass, in grams, of one atom of iron? (NA = 6.022 × 1023 mol-1)


A) 6.02 × 1023 g
B) 1.66 × 10-24 g
C) 9.27 × 10-23 g
D) 55.85 g
E) 55.85 × 10-23 g

F) B) and C)
G) C) and D)

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The molecular formula is a whole number multiple of the empirical formula.

A) True
B) False

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What is the coefficient of O2 when the following equation is properly balanced with the smallest set of whole numbers? ________ C2H4 + ________ O2 → ________ CO2 + ________ H2O


A) 1
B) 2
C) 3
D) 4
E) 6

F) A) and C)
G) B) and C)

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Ammonia reacts with oxygen to form nitrogen monoxide and water. What is the theoretical yield and the percent yield if 17.25 g of nitrogen monoxide is produced when 21.50 g of ammonia and 26.85 g of oxygen react? (Show all your work)

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Theoretical yield = ...

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Calculate the formula mass of potassium permanganate, KMnO4.


A) 149.91 amu
B) 79.41 amu
C) 127.41 amu
D) 158.04 amu
E) 174.04 amu

F) A) and B)
G) A) and C)

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Sulfur trioxide can react with atmospheric water vapor to form sulfuric acid that falls as acid rain. Calculate the mass in grams of 3.65 × 1020 molecules of sulfur trioxide.


A) 6.06 × 10-4 g
B) 2.91 × 10-2 g
C) 4.85 × 10-2 g
D) 20.6 g
E) 1650 g

F) All of the above
G) C) and D)

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How many grams of calcium metal is required to react with 7.75 g water to produce calcium hydroxide and hydrogen gas?


A) 8.62 g
B) 34.5 g
C) 4.31 g
D) 40.1 g
E) 17.2 g

F) B) and E)
G) None of the above

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When octane (C8H18) is burned in a particular internal combustion engine, the yield of products (carbon dioxide and water) is 93%. What mass of carbon dioxide will be produced in this engine when 15.0 g of octane is burned with 15.0 g of oxygen gas?


A) 13 g
B) 12 g
C) 21 g
D) 54 g
E) 43 g

F) A) and B)
G) B) and D)

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What is the theoretical yield of vanadium, in moles, that can be produced by the reaction of 2.0 mole of V2O5 with 6.0 mole of calcium based on the following chemical equation? V2O5(s) + 5Ca(l) → 2V(l) + 5CaO(s)


A) 1.0 mol
B) 1.6 mol
C) 2.0 mol
D) 2.4 mol
E) 4.0 mol

F) B) and C)
G) None of the above

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A certain compound of bromine and fluorine is used to make UF6, which is an important chemical in the processing and reprocessing of nuclear fuel. The compound contains 58.37 mass percent bromine. What is its empirical formula?


A) BrF
B) BrF2
C) Br2F3
D) Br3F
E) BrF3

F) B) and E)
G) A) and D)

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What is the empirical formula for a 100-g sample containing 87.42 g of nitrogen and 12.58 g of hydrogen?


A) NH
B) N2H
C) NH2
D) NH3
E) N7H

F) A) and B)
G) A) and C)

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What is the percent sodium in sodium carbonate?


A) 43.4%
B) 11.3%
C) 45.3%
D) 27.7%
E) 21.7%

F) None of the above
G) A) and E)

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What is the maximum number of grams of ammonia, NH3, which can be obtained from the reaction of 10.0 g of H2 and 80.0 g of N2? N2 + 3H2 → 2NH3


A) 34.1 g
B) 48.6 g
C) 56.3 g
D) 90.0 g
E) 97.3 g

F) C) and D)
G) A) and E)

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