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Consider an electrochemical cell constructed from the following half cells, linked by a KCl salt bridge. - a Fe electrode in 1.0 M FeCl2 solution - a Sn electrode in 1.0 M Sn(NO3) 2 solution When the cell is running spontaneously, which choice includes only true statements and no false ones


A) The tin electrode loses mass and the tin electrode is the cathode.
B) The tin electrode gains mass and the tin electrode is the cathode.
C) The iron electrode gains mass and the iron electrode is the anode.
D) The iron electrode loses mass and the iron electrode is the cathode.
E) The iron electrode gains mass and the iron electrode is the cathode.

F) None of the above
G) A) and C)

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Find the emf of the cell described by the cell diagram Fe | Fe2+ (1.500M) || Au3+ (0.00400M) | Au.


A) 1.99 V
B) 1.89 V
C) 1.94 V
D) 1.66 V
E) 1.91 V

F) A) and E)
G) A) and C)

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B

Determine the cell diagram for the reaction below. Assume platinum electrodes are used when no other solid is present. Cl2(g) + Sn2+(aq) \rarr Sn4+(aq) + 2Cl-(aq)


A) Pt(s) | Cl2(g) | Cl-(aq) || Sn2+(aq) , Sn4+(aq) | Pt(s)
B) Pt(s) | Sn2+(aq) , Sn4+(aq) || Cl2(g) | Cl-(aq) | Pt(s)
C) Pt(s) | Sn4+(aq) , Sn2+(aq) || Cl-(aq) | Cl2(g) | Pt(s)
D) Pt(s) | Cl-(g) | Cl2(aq) || Sn4+(aq) , Sn2+(aq) | Pt(s)
E) Pt(s) | Cl2(g) | Sn2+(aq) || Sn4+(aq) , Cl-(aq) | Pt(s)

F) None of the above
G) C) and D)

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Write the formula of the strongest oxidizing agent given the following standard reduction potentials in acid solution: O2+4H++4e2H2OE=+1.23 VSn4++2eSn2+E=+0.13 VZn2++2eZn( s) E=0.76 V\begin{array}{ll}\mathrm{O}_{2}+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_{2} \mathrm{O} & \mathrm{E}^{\circ}=+1.23 \mathrm{~V} \\\mathrm{Sn}^{4+}+2 \mathrm{e}^{-} \rightarrow \mathrm{Sn}^{2+} & \mathrm{E}^{\circ}=+0.13 \mathrm{~V} \\\mathrm{Zn}^{2+}+2 \mathrm{e}^{-} \rightarrow \mathrm{Zn}(\mathrm{~s}) & \mathrm{E}^{\circ}=-0.76 \mathrm{~V}\end{array}


A) Sn4+
B) O2
C) Zn2+
D) 2H2O
E) None of the above

F) A) and C)
G) D) and E)

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Which of these metals will be oxidized in hydrochloric acid under standard conditions at 25 \circ C


A) Ag
B) Au
C) Hg
D) Cu
E) Zn

F) A) and D)
G) B) and D)

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Which one of the following reagents is capable of oxidizing Br- (aq) to Br2(l) under standard-state conditions


A) I- (aq)
B) NO3- (aq)
C) Ag+ (aq)
D) Al3+ (aq)
E) Au3+ (aq)

F) B) and E)
G) A) and C)

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A current of 2.50 A was passed through an electrolytic cell containing molten CaCl2 for 4.50 hours. How many moles of calcium metal should be deposited


A) 5.83 * 10-5 mol
B) 0.210 mol
C) 0.420 mol
D) 0.840 mol
E) 1.95 * 109 mol

F) A) and C)
G) C) and E)

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If the measured voltage of the cell Zn(s) | Zn2+(aq) || Ag+(aq) | Ag(s) is 1.37 V when the concentration of Zn2+ ion is 0.010 M, what is the Ag+ ion concentration


A) 2.5 M
B) 4.0* 10-9 M
C) 6.2 * 10-3 M
D) 2.6 * 10-51 M
E) 6.2 * 10-5 M

F) C) and D)
G) A) and C)

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A galvanic cell has the overall reaction: Zn(s) + 2Eu(NO3) 3(aq) \rarr Zn(NO3) 2(aq) + 2Eu(NO3) 2(aq) Which is the half reaction occurring at the anode


A) NO3-(aq) + 4H+(aq) + 3e- \rarr NO(g) + 2H2O(l)
B) NO2(g) + H2O(l) \rarr NO3-(aq) + 2H+(aq) + e-
C) Zn(s) \rarr Zn2+(aq) + 2e-
D) Eu3+(aq) + e- \rarr Eu2+
E) Zn(s) + 2e- \rarr Zn2+(aq) -

F) A) and E)
G) B) and C)

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C

Complete and balance the following redox equation. When properly balanced using the smallest whole-number coefficients, the coefficient of S is H2S + HNO3 \rarr S + NO (acidic solution)


A) 1.
B) 2.
C) 3.
D) 5.
E) 6.

F) A) and B)
G) C) and D)

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How many coulombs would be required to electroplate 35.0 grams of chromium by passing an electrical current through a solution containing CrCl3


A) 6.50 * 104 C
B) 2.16 * 104 C
C) 6.40 * 104 C
D) 1.95 * 105 C
E) 1.01 * 107 C

F) A) and B)
G) C) and E)

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Consider a voltaic cell based on the following cell reaction: Ni(s) + At2(s) \rarr Ni2+(aq) + 2At- (aq) Given that the standard cell emf is 0.55 V, what is the standard reduction potential for astatine [E \circ (Ni2+/Ni) = -0.25 V]


A) 0.80 V
B) 0.30 V
C) -0.30 V
D) -0.80 V
E) 0.43 V

F) B) and E)
G) A) and E)

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H2(g) will form when Sn is placed in 1.0 M HCl.

A) True
B) False

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Suppose the reaction Pb(s) + 2H+(aq) \rarr Pb2+(aq) + H2(g) is carried out at pH = 4.00 and at a hydrogen gas pressure of 1.00 atm. The concentration of lead(II) ions that causes this reaction to be at equilibrium is


A) 2.5 M.
B) 1.6 * 10-2 M.
C) 2.5 * 10-4 M.
D) 1.6 * 10-6 M.
E) 0.40 M.

F) A) and B)
G) D) and E)

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C

Using a table of standard electrode potentials, decide which of the following statements is completely true.


A) Cu2+ can oxidize H2, and Fe can reduce Mn2+.
B) Ni2+ can oxidize Cu2+, and Fe2+ can reduce H+.
C) Fe2+ can oxidize H2, and Fe2+ can reduce Au3+.
D) Br2 can oxidize Ni, and H2 can reduce Mn2+.
E) H+ can oxidize Fe, and Ni can reduce Br2.

F) B) and C)
G) None of the above

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How many grams of chromium would be electroplated by passing a constant current of 5.2 amperes through a solution containing CrCl3 for 45.0 min


A) 9.3 * 10-4 g
B) 0.042 g
C) 2.5 g
D) 24 g
E) 2.3 * 1010 g

F) D) and E)
G) B) and E)

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Determine the cell diagram for the reaction below. Assume a platinum electrode is used when no other solid is present. 2Fe2+(aq) + Pb2+(aq) \rarr 2Fe3+(aq) + Pb(s)


A) Pt(s) | Fe2+(aq) , Fe3+(aq) || Pb2+(aq) | Pb(s)
B) Pb(s) | Pb2+(aq) || Fe2+(aq) , Fe3+(aq) | Pt(s)
C) Pt(s) | Fe3+(aq) , Fe2+(aq) || Pb(s) | Pb2+(aq) | Pt(s)
D) Pt(s) | Pb2+(aq) | Pb(s) || Fe2+(aq) , Fe3+(aq) | Pt(s)
E) Pt(s) | Fe2+(aq) , Pb2+(aq) || Fe3+(aq) | Pb(s)

F) B) and D)
G) A) and C)

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How many moles of H2 are produced by 5.00 A of current passing through a cell containing aqueous NaCl for 4.00 * 102 s


A) 0.0104 mol
B) 0.0124 mol
C) 0.0144 mol
D) 0.0164 mol
E) None of the above

F) A) and E)
G) A) and C)

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Complete and balance the following redox equation. The sum of the smallest whole-number coefficients is Br2 \rarr BrO3- + Br- (basic solution)


A) 9.
B) 12.
C) 18.
D) 21.
E) None of the above.

F) A) and B)
G) C) and E)

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Consider an electrochemical cell based on the following cell diagram: Pt | Pu3+(aq) , Pu4+(aq) || Cl2(g) , Cl- (aq) | Pt Given that the standard cell emf is 0.35 V and that the standard reduction potential of chlorine is 1.36 V, what is the standard reduction potential E \circ (Pu4+/Pu3+)


A) 2.37 V
B) 1.01 V
C) -1.71 V
D) -1.01 V
E) 1.71 V

F) B) and D)
G) C) and D)

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